Title Ice nucleation and cloud microphysical properties in tropical tropopause layer cirrus
Author Jensen, E.J.; Pfister, L.; Bui, T.P.; Lawson, P.; Baumgardner, D.
Author Affil Jensen, E.J., NASA, Ames Research Center, Moffett Field, CA. Other: SPEC; Universidad Nacional Autonoma de Mexico, Mexico
Source Atmospheric Chemistry and Physics, 10(3), p.1369-1384, . Publisher: Copernicus, Katlenburg-Lindau, International. ISSN: 1680- 7316
Publication Date 2010
Notes In English. Published in Atmospheric Chemistry and Physics Discussions: 1 October 2009, http://www.atmos-chem-phys- discuss.net/9/20631/2009/acpd-9-20631- 2009.html ; accessed in May, 2011. 62 refs. GeoRef Acc. No: 310101
Index Terms aerosols; aerial surveys; airborne radar; clouds (meteorology); crystals; drying; distribution; human activity; ice; ice crystals; lasers; lidar; nucleation; particles; physical properties; radar; remote sensing; supersaturation; temperature; airborne methods; ammonium sulfates; aqueous solutions; clouds; dehydration; dynamics; laser methods; lidar methods; organic compounds; radar methods; size; tropical environment; troposphere; very low temperature
Abstract In past modeling studies, it has generally been assumed that the predominant mechanism for nucleation of ice in the uppermost troposphere is homogeneous freezing of aqueous aerosols. However, recent in situ and remote-sensing measurements of the properties of cirrus clouds at very low temperatures in the tropical tropopause layer (TTL) are broadly inconsistent with theoretical predictions based on the homogeneous freezing assumption. The nearly ubiquitous occurrence of gravity waves in the TTL makes the predictions from homogeneous nucleation theory particularly difficult to reconcile with measurements. These measured properties include ice number concentrations, which are much lower than theory predicts; ice crystal size distributions, which are much broader than theory predicts; and cloud extinctions, which are much lower than theory predicts. Although other explanations are possible, one way to limit ice concentrations is to have on the order of 50 L-1 effective ice nuclei (IN) that could nucleate ice at relatively low supersaturations. We suggest that ammonium sulfate particles, which would be dry much of the time in the cold TTL, are a potential IN candidate for TTL cirrus. However, this mechanism remains to be fully quantified for the size distribution of ammonium sulfate (possibly internally mixed with organics) actually present in the upper troposphere. Possible implications of the observed cloud microphysical properties for ice sedimentation, dehydration, and cloud persistence are also discussed.
URL http://www.atmos-chem-phys.net/10/1369/2010/acp-10-1369-2010.pdf
Publication Type journal article
Record ID 65006752